Fretting, fretting corrosion and fretting mechanisms

fretting corrosion
Fretting corrosion. Credit for image: Felix Prigge, Fabian Schwack, Artjom Byckov

Revision for “Fretting, fretting corrosion and fretting mechanisms” created on February 21, 2019 @ 21:10:08

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Fretting, fretting corrosion and fretting mechanisms
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<h2 style="text-align: justify;">What is fretting?</h2> <p style="text-align: justify;">Fretting or fretting wear is a specific <a href="http://www.tribonet.org/wiki/wear/">wear</a> type which is characterized by low amplitude oscillating sliding between bodies, which are nominally at rest [1] (for example due to vibration, cyclic stresses, etc). The amplitude of sliding may vary from tens of mircons (in bolted joints, electrical contacts) to tens of nanometers (in <a href="https://en.wikipedia.org/wiki/Microelectromechanical_systems" target="_blank" rel="noopener">MEMS</a>). <span class="topic-highlight">Fretting typically</span> appears as pits or grooves surrounded by corrosion products. <span class="topic-highlight">Fretting</span> is usually accompanied by <span id="p242"></span>corrosion (in a corrosive environment).</p> <p id="p0840" style="text-align: justify;">In <span class="topic-highlight">fretting</span> there is no macroscopic sliding. The surfaces are nominally in static contact in the central region of a contact (for a ball on flat case), where the normal pressure is high. At the periphery, where the pressure is low and the tangential traction is sufficiently high to overcome the static friction, microslip occurs. Figure 1 shows <em><strong>stick and slip zones</strong></em> in a <span class="topic-highlight">fretting</span> contact.</p> [caption id="attachment_23971" align="aligncenter" width="830"]<img class="size-full wp-image-23971" src="http://www.tribonet.org/wp-content/uploads/2018/10/Fretting.jpg" alt="fretting" width="830" height="508" /> Figure 1. Stresses in a fretting contact[/caption] <p style="text-align: justify;">Fretting is a combination of <a href="http://www.tribonet.org/wiki/abrasive-wear/">abrasive</a> and <a href="http://www.tribonet.org/wiki/adhesive-wear/">adhesive</a> wear, where under applied normal load adhesive junctions occur, while the oscillating motion causes rupture of the material in a form of <a href="http://www.tribonet.org/wiki/wear-particles/">debris</a>. Debris typically get entrapped in the contact and form rolls which act like bearings [2]. This may lead to reduction of coefficient of friction with time.</p> <h2 style="text-align: justify;">Fretting corrosion</h2> <p style="text-align: justify;">Fretting is commonly combined with corrosion, a wear mode known as fretting corrosion. Due to rupture of the material and formation of debris, fresh surface is exposed to air which subsequently is getting oxidized (depending on the <a href="https://en.wikipedia.org/wiki/Microelectromechanical_systems" target="_blank" rel="noopener">inertness of the material</a>). In case of steel, the iron oxide is very hard and thus acts as an abrasive. Since the particles cannot escape the contact, they initiate abrasive wear and subsequent oxidation and the process continues. This may lead to elevated wear volumes, as compared to abrasive or adhesive wear modes themselves.</p> <h2>Fretting test</h2> <p style="text-align: justify;">Fretting tests are used to determine the effects of several fretting parameters on the performance of materials. These parameters include differing materials, relative displacement amplitudes, normal force at the fretting contact, alternating tangential force, the contact geometry, surface integrity parameters such as finish, and the environment. The results may be used as a guide in selecting material combinations, design stress levels, lubricants, and coatings to alleviate or eliminate fretting concerns in new or existing designs. Various <a href="https://rtec-instruments.com/fretting-tester.html">fretting testers</a> are commercially available. In the video below a typical fretting test operation is shown:</p> [embed]https://www.youtube.com/watch?v=YCD3j4BPPY4[/embed] <h2 style="text-align: justify;">Fretting corrosion mechanism</h2> <div style="text-align: justify;"> Typically, three stages of fretting can be distinguished [3]: <p id="para1125">1. In the the first stage metallic contact between two surfaces occurs on asperity level (cold welding, adhesion). This happens, if the protective oxide layer is broken down, so that highly reactive bare materials come into contact. The contact occurs at few sites, called <em>asperities</em> (surface protrusions).</p> 2. In the second stage debris are generated and subsequently oxidated. It is difficult for particles to escape the contact since the amplitude of motion is limited and therefore they act as abrasives, which may increase wear rates. 3. In the third stage, fretting fatigue occurs. Due to repeated loading and shear stresses, the elevated stress area in fretting occurs on the sides of the loaded area. Therefore, the crack initiates at the boundaries of the fretting area and propagates inside. <h2 style="text-align: justify;">Fretting fatigue</h2> <p style="text-align: justify;">In fretting contact surfaces are worn and, at the same time, they are affected by cyclic friction stress. <a href="http://www.tribonet.org/wiki/fatigue-wear/">Fatigue</a> with <span class="topic-highlight">fretting</span> is called <span class="topic-highlight">fretting</span> fatigue [4]. The friction stress is maximum on the contact surface of the material and decreases drastically toward the inside of the material. Therefore, <span class="topic-highlight">fretting</span> fatigue crack growth behavior differs significantly from fatigue crack growth behavior in friction-less fatigue [5]. In <span class="topic-highlight">fretting</span> fatigue, the growth rate of a crack near the contact surface decreases drastically with increasing crack length. Then, after showing a minimum value, it <span id="p166"></span>is in accord with the plain fatigue crack growth rate. The <span class="topic-highlight">fretting</span> fatigue strength is often half or less of the plain fatigue strength and it will not become higher even if the tensile strength of the material is increased [5].</p> <p style="text-align: justify;"><span class="topic-highlight">Fretting</span> fatigue life is shorter than plain fatigue life. In <span class="topic-highlight">fretting</span> fatigue, a crack easily nucleates due to friction stress even at a small stress amplitude at which plain fatigue failure may not occur, and the crack grows, leading to material failure. In orthopedic implants, <span class="topic-highlight">fretting</span> occurs where two materials come into contact with each other; such as in bone plates or screws.</p> <h2 style="text-align: justify;">Factors affecting fretting</h2> <section id="cesec331">Fretting resistance is not an intrinsic property of a material, or even of a material couple. For example, depending on the amplitude of the displacement or on the normal load, the fretting condition can be partial slip, gross slip or mixed slip. These three situations induce different local loading on the surface. Moreover, the environmental condition may have a large effect. There are several factors affecting fretting behavior of a contact [3]: <ul> <li style="text-align: justify;">Contact load: Wear is a linear function of load and <span class="topic-highlight">fretting</span> would, therefore, increase with increased load as long as the amplitude is not reduced.</li> <li style="text-align: justify;">Amplitude: No measurable threshold amplitude exists below which <span class="topic-highlight">fretting</span> does not occur. An upper threshold limit, however, may exist at which the transition of wear rate to the regular sliding type occurs.</li> <li style="text-align: justify;">Number of cycles: The degree of <span class="topic-highlight">fretting</span> increases with the number of cycles. An incubation period is reported to exist during which the damage is negligible. This period is followed by a steady-state period with a constant wear rate. Further, the rate of <span class="topic-highlight">fretting</span> wear is increased.</li> <li style="text-align: justify;">Temperature: Temperature has a significant impact on the rate of chemical reactions and therefore on oxidation of materials. At elevated temperatures, the oxide formation rate is high and the oxide layer acts as a protective layer. This layer protects bare materials from coming into contact and forming adhesive junctions (cold welding). Thus wear rate is reduced.</li> <li style="text-align: justify;">Relative humidity: Typically, increased humidity reduces the fretting corrosion. It is believed to be a consequence of increased oxidation rate in presence of water and thus formation of a protective layer.</li> <li>Inertness of materials [6]: ability of materials to react with oxygen directly impacts the fretting fatigue.</li> </ul> &nbsp; <h2>References</h2> <p style="text-align: justify;">[1] <a href="https://onlinelibrary.wiley.com/doi/abs/10.1002/maco.19750260224" target="_blank" rel="noopener">Fretting Corrosion</a>. Von <i>R. B. Waterhouse</i>. 253 S. 306 Abb., 13 Tab. 1972, Pergamon Press, Oxford, New York, Toronto, Sydney, Braunschweig</p> <p style="text-align: justify;">[2] Friction Science and Technology: From Concepts to Applications, Peter J. Blau,</p> <p style="text-align: justify;">[3] <cite>Zaki Ahmad, in <a class="anchor" href="https://www.sciencedirect.com/science/book/9780750659246" data-hack="#"><span class="anchor-text">Principles of Corrosion Engineering and Corrosion Control</span></a>, 2006</cite></p> <p id="aa-tp-snippet-bk-title" style="text-align: justify;">[4] <a class="anchor" href="https://www.sciencedirect.com/science/article/pii/B9781845694340500061" data-hack="#"><span class="anchor-text">Mechanical testing of metallic biomaterials</span></a>, N. Maruyama, in <span class="anchor-text">Metals for Biomedical Devices</span>, 2010</p> <p style="text-align: justify;">[5] <span class="st">R.B. <em>Waterhouse</em>, </span><a id="0043164884900085" class="anchor article-content-title u-margin-xs-top u-margin-s-bottom" href="https://www.sciencedirect.com/science/article/pii/0043164884900085"><span class="anchor-text"><span class="js-article-title">Fretting wear</span></span></a>, Wear, 1984</p> [6] Engineering Tribology, Gwidon W. Stachowiak, Andrew W. Batchelor, Third Edition, 2005 </section></div>
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1 Comment

  1. hello.
    i want to enquire whether fretting wear can occur in suspension front forks of motor cycles.
    as the front forks continuously undergo reciprocating motion, under contact between hard chrome plating and various sealings generally made up of NBR rubber,PTFE etc, is there any chance of fretting wear on the front forks?

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